Nematic ordering of SWNT in meso-structured thin liquid films of polystyrenesulfonate

The formation of nematic-like islands of single-walled carbon nanotubes (SWNT) in polystyrenesulfonate (PSS) dispersions confined into nanometrically thin films is reported. The SWNT are observed to assemble into orientationally ordered phases, where the intertube distance, as measured via transmiss...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 49 vom: 16. Dez., Seite 14963-70
1. Verfasser: Itzhak-Cohen, Racheli (VerfasserIn)
Weitere Verfasser: Nativ-Roth, Einat, Levi-Kalisman, Yael, Josef, Elinor, Szleifer, Igal, Yerushalmi-Rozen, Rachel
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S. Nanotubes, Carbon Polystyrenes polystyrene sulfonic acid 70KO0R01RY
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520 |a The formation of nematic-like islands of single-walled carbon nanotubes (SWNT) in polystyrenesulfonate (PSS) dispersions confined into nanometrically thin films is reported. The SWNT are observed to assemble into orientationally ordered phases, where the intertube distance, as measured via transmission electron microscopy at cryogenic temperatures, matches the polyelectrolyte's bulk correlation length deduced from X-ray scattering. The micrometers-long islands of orientationally ordered carbon nanotubes are observed in both SWNT and double-walled carbon nanotubes (DWNT) but not in specimens prepared from similar dispersions of multiwalled carbon nanotubes (MWNT). These observations, together with relaxation and rheological experiments, suggest that the orientational ordering may result from coupling between confinement of the polymer-wrapped SWNT and DWNT and the microstructure of the solvated polyelectrolyte 
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700 1 |a Nativ-Roth, Einat  |e verfasserin  |4 aut 
700 1 |a Levi-Kalisman, Yael  |e verfasserin  |4 aut 
700 1 |a Josef, Elinor  |e verfasserin  |4 aut 
700 1 |a Szleifer, Igal  |e verfasserin  |4 aut 
700 1 |a Yerushalmi-Rozen, Rachel  |e verfasserin  |4 aut 
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