Electrografting of alkyl films at low driving force by diverting the reactivity of aryl radicals derived from diazonium salts

Alkyl and partial perfluoroalkyl groups are strongly attached to carbon surfaces through (i) the abstraction of the iodine atom from an iodoalkane by the sterically hindered 2,6-dimethylphenyl radical and (ii) the reaction of the ensuing alkyl radical with the carbon surface. Since the 2,6-dimethylp...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 46 vom: 25. Nov., Seite 13907-13
1. Verfasser: Hetemi, Dardan (VerfasserIn)
Weitere Verfasser: Kanoufi, Frédéric, Combellas, Catherine, Pinson, Jean, Podvorica, Fetah I
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Diazonium Compounds Free Radicals Membranes, Artificial Xylenes 2,6-xylenol I8N0RO87OV