An unconventional method for measuring the Tc L3-edge of technetium compounds

Tc L3-edge XANES spectra have been collected on powder samples of SrTcO3 (octahedral Tc(4+)) and NH4TcO4 (tetrahedral Tc(7+)) immobilized in an epoxy resin. Features in the Tc L3-edge XANES spectra are compared with the pre-edge feature of the Tc K-edge as well as other 4d transition metal L3-edges....

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Journal of synchrotron radiation. - 1994. - 21(2014), Pt 6 vom: 01. Nov., Seite 1275-81
1. Verfasser: Blanchard, Peter E R (VerfasserIn)
Weitere Verfasser: Reynolds, Emily, Kennedy, Brendan J, Ling, Chris D, Zhang, Zhaoming, Thorogood, Gordon, Cowie, Bruce C C, Thomsen, Lars
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Journal of synchrotron radiation
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Tc L3-edge XANES crystal field splitting radioactive materials technetium oxides