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231224s2014 xx |||||o 00| ||eng c |
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7 |
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|a 10.1021/la5030873
|2 doi
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|a eng
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| 100 |
1 |
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|a Jia, Yong-Guang
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Thermoresponsiveness of copolymers bearing cholic acid pendants induced by complexation with β-cyclodextrin
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| 264 |
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|c 2014
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 14.05.2015
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|a Date Revised 07.10.2014
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Copolymers of N-alkylacrylamides and methacrylate bearing cholic acid pendant groups were synthesized via radical polymerization. The cholic acid pendant groups of such copolymers can form complexes with β-cyclodextrin, and the effect of complexation on their thermoresponsive properties was studied. The phase transition temperatures (transition from hydrophilic to hydrophobic state) of the copolymers gradually increase with the addition of β-cyclodextrin, due to the complexation of the cholic acid guest with the β-cyclodextrin host. The increase of the phase transition temperature may be reversed by the addition of a competing guest molecule, potassium 1-adamantylcarboxylate. The host-guest complexation provides a straightforward way to vary the thermoresponsive properties of such copolymers
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|a Journal Article
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|a Zhu, X X
|e verfasserin
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 30(2014), 39 vom: 07. Okt., Seite 11770-5
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|x 1520-5827
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|g volume:30
|g year:2014
|g number:39
|g day:07
|g month:10
|g pages:11770-5
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|u http://dx.doi.org/10.1021/la5030873
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