Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors
A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demo...
| Publié dans: | Organometallics. - 1998. - 33(2014), 16 vom: 25. Aug., Seite 4169-4172 |
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| Auteur principal: | |
| Autres auteurs: | , , |
| Format: | Article |
| Langue: | English |
| Publié: |
2014
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| Accès à la collection: | Organometallics |
| Sujets: | Journal Article |
| Résumé: | A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demonstrate the stability of these compounds and the marked difference in reduction potentials with varying ligand scaffolds |
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| Description: | Date Revised 21.10.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 0276-7333 |