Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors

A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demo...

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Bibliographische Detailangaben
Veröffentlicht in:Organometallics. - 1998. - 33(2014), 16 vom: 25. Aug., Seite 4169-4172
1. Verfasser: Johnson, Miles W (VerfasserIn)
Weitere Verfasser: DiPasquale, Antonio G, Bergman, Robert G, Toste, F Dean
Format: Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Organometallics
Schlagworte:Journal Article
Beschreibung
Zusammenfassung:A series of gold(III) complexes supported by pyridine-based bis(amidate), bis(carboxylate), and bis(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demonstrate the stability of these compounds and the marked difference in reduction potentials with varying ligand scaffolds
Beschreibung:Date Revised 21.10.2021
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:0276-7333