Photoinduced diffusion through polymer networks
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 26(2014), 37 vom: 08. Okt., Seite 6497-502 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. fluorescence recovery after photobleaching (FRAP) mass transport photoinduced diffusion polymer networks stimuli-responsive polymers Acrylates Polymers mehr... |
| Zusammenfassung: | © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Photomediated addition-fragmentation chemistry is applied to demonstrate the precisely controlled diffusion of chemical species through polymer networks. Fluorescent groups connected to polymer networks by allyl sulfide moieties become mobile upon irradiation with UV light due to radical-mediated addition-fragmentation bond exchange. Photoinduced transport through the bulk, into solution, and across film interfaces is demonstrated |
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| Beschreibung: | Date Completed 16.06.2015 Date Revised 30.09.2020 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201402097 |