Polymer-assisted self-assembly of superparamagnetic iron oxide nanoparticles into well-defined clusters : controlling the collective magnetic properties

The combination of superstructure-forming amphiphilic block copolymers and superparamagnetic iron oxide nanoparticles produces new nano/microcomposites with unique size-dependent properties. Herein, we demonstrate the controlled clustering of superparamagnetic iron oxide nanoparticles (SPIOs) rangin...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 37 vom: 23. Sept., Seite 11190-6
1. Verfasser: Schmidtke, Christian (VerfasserIn)
Weitere Verfasser: Eggers, Robin, Zierold, Robert, Feld, Artur, Kloust, Hauke, Wolter, Christopher, Ostermann, Johannes, Merkl, Jan-Philip, Schotten, Theo, Nielsch, Kornelius, Weller, Horst
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Cadmium Compounds Ferric Compounds Polymers Selenium Compounds Sulfides Surface-Active Agents cadmium sulfide 057EZR4Z7Q mehr... ferric oxide 1K09F3G675 cadmium selenide A7F646JC5C
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520 |a The combination of superstructure-forming amphiphilic block copolymers and superparamagnetic iron oxide nanoparticles produces new nano/microcomposites with unique size-dependent properties. Herein, we demonstrate the controlled clustering of superparamagnetic iron oxide nanoparticles (SPIOs) ranging from discretely encapsulated SPIOs to giant clusters, containing hundreds or even more particles, using an amphiphilic polyisoprene-block-poly(ethylene glycol) diblock copolymer. Within these clusters, the SPIOs interact with each other and show new collective properties, neither obtainable with singly encapsulated nor with the bulk material. We observed cluster-size-dependent magnetic properties, influencing the blocking temperature, the magnetoviscosity of the liquid suspension, and the r2 relaxivity for magnetic iron oxide nanoparticles. The clustering methodology can be expanded also to other nanoparticle materials [CdSe/CdS/ZnS core/shell/shell quantum dots (QDs), CdSe/CdS quantum dots/quantum rods (QDQRs), gold nanoparticles, and mixtures thereof] 
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700 1 |a Eggers, Robin  |e verfasserin  |4 aut 
700 1 |a Zierold, Robert  |e verfasserin  |4 aut 
700 1 |a Feld, Artur  |e verfasserin  |4 aut 
700 1 |a Kloust, Hauke  |e verfasserin  |4 aut 
700 1 |a Wolter, Christopher  |e verfasserin  |4 aut 
700 1 |a Ostermann, Johannes  |e verfasserin  |4 aut 
700 1 |a Merkl, Jan-Philip  |e verfasserin  |4 aut 
700 1 |a Schotten, Theo  |e verfasserin  |4 aut 
700 1 |a Nielsch, Kornelius  |e verfasserin  |4 aut 
700 1 |a Weller, Horst  |e verfasserin  |4 aut 
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