Effect of activator on the structure and desulphurization efficiency of sludge-activated carbon

Sludge-activated carbons (SACs) prepared with excess of activated sludge are used to solve the problems of sludge disposal and odour pollution in a sewage treatment plant. For the preparation, ZnCl2, KOH and H2SO4 are used as activators, respectively. The structure of the SACs are characterized by s...

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Veröffentlicht in:Environmental technology. - 1993. - 35(2014), 17-20 vom: 21. Sept., Seite 2575-81
1. Verfasser: Li, Fen (VerfasserIn)
Weitere Verfasser: Yan, Bo, Zhang, Yanping, Zhang, Linhuan, Lei, Tao
Format: Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Chlorides Hydroxides Potassium Compounds Sewage Zinc Compounds Charcoal 16291-96-6 zinc chloride mehr... 86Q357L16B potassium hydroxide WZH3C48M4T Hydrogen Sulfide YY9FVM7NSN
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520 |a Sludge-activated carbons (SACs) prepared with excess of activated sludge are used to solve the problems of sludge disposal and odour pollution in a sewage treatment plant. For the preparation, ZnCl2, KOH and H2SO4 are used as activators, respectively. The structure of the SACs are characterized by scanning electron microscope, X-ray photoelectron spectrometer, specific surface area and pore structure technologies, and the adsorption performance of H2S is investigated. Results indicate that the desulphurization activity of SACs, whose activators are ZnCl2 and KOH (SACZ and SACK), is better than that of carbon with H2SO4 as the activator (SACH). The breakthrough time of SACZ and SACK is up to 86 min, the sulphur capacity is 7.7 mg/cm3, and the maximal iodine value is 409.95 mg/g. While the breakthrough time of SACH is only 26 min with the sulphur capacity of 2.3 mg/cm3. A large percentage of pore volume with a diameter of 2-5 nm in the total pore volume is conductive to the desulphurization reaction. The large amount of surface acid functional groups is also helpful to the adsorption of H2S. The desulphurization activity of SACZ and SACK is superior over that of commercial-activated carbon 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Chlorides  |2 NLM 
650 7 |a Hydroxides  |2 NLM 
650 7 |a Potassium Compounds  |2 NLM 
650 7 |a Sewage  |2 NLM 
650 7 |a Zinc Compounds  |2 NLM 
650 7 |a Charcoal  |2 NLM 
650 7 |a 16291-96-6  |2 NLM 
650 7 |a zinc chloride  |2 NLM 
650 7 |a 86Q357L16B  |2 NLM 
650 7 |a potassium hydroxide  |2 NLM 
650 7 |a WZH3C48M4T  |2 NLM 
650 7 |a Hydrogen Sulfide  |2 NLM 
650 7 |a YY9FVM7NSN  |2 NLM 
700 1 |a Yan, Bo  |e verfasserin  |4 aut 
700 1 |a Zhang, Yanping  |e verfasserin  |4 aut 
700 1 |a Zhang, Linhuan  |e verfasserin  |4 aut 
700 1 |a Lei, Tao  |e verfasserin  |4 aut 
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