|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM241148170 |
| 003 |
DE-627 |
| 005 |
20231224123624.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2014 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la500114k
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0803.xml
|
| 035 |
|
|
|a (DE-627)NLM241148170
|
| 035 |
|
|
|a (NLM)25141225
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Yiapanis, George
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Nanoscale wetting and fouling resistance of functionalized surfaces
|b a computational approach
|
| 264 |
|
1 |
|c 2014
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 15.05.2015
|
| 500 |
|
|
|a Date Revised 09.09.2014
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a A computational modeling methodology has been developed and employed to characterize the nanoscale wettability and antifouling properties of functionalized hard and deformable surfaces, with a specific focus on poly(ethylene glycol) grafted substrates and their resistance to graphitic carbons. Empirical evidence suggests that the antifouling behavior of polyethylene PEG is associated with two main mechanisms: steric repulsions and hydration via formation of a structured water layer. However, there is also little attention paid to the contribution of steric repulsion vs surface hydration. We examine these two mechanisms through a combination of in silico contact angle and force measurements at the nanoscale level. We investigate the properties of the grafted functional chains and the underlying substrate, responsible for resisting surface deposition of graphitic contaminants in aqueous solution. Our results reveal that the fouling-release efficiency is enhanced when PEG chains are grafted onto hard hydrophilic substrates such as silica in contrast to deformable polymer substrates where surface modifications are effectively mitigated during interfacial contact with a hard contaminant. We conclude that the contribution of steric repulsion vs surface hydration to the antifouling ability of surfaces is strongly dependent on the nanoscale structure and deformability of the substrate. This generic method can be applied to examine individual contribution of steric repulsions and surface hydration to antifouling performance of grafted chains
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Maclaughlin, Shane
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Evans, Evan J
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yarovsky, Irene
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 30(2014), 35 vom: 09. Sept., Seite 10617-25
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:30
|g year:2014
|g number:35
|g day:09
|g month:09
|g pages:10617-25
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la500114k
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 30
|j 2014
|e 35
|b 09
|c 09
|h 10617-25
|