Phosphonate removal from discharged circulating cooling water using iron-carbon micro-electrolysis

Phosphonate is a commonly used corrosion and scale inhibitor for a circulating cooling water (CCW) system. Its discharge could cause eutrophication of receiving waters. The iron-carbon (Fe/C) micro-electrolysis technology was used to degrade and remove phosphonate from discharged CCW. The influences...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 70(2014), 3 vom: 28., Seite 524-32
1. Verfasser: Zhou, Zhen (VerfasserIn)
Weitere Verfasser: Qiao, Weimin, Lin, Yangbo, Shen, Xuelian, Hu, Dalong, Zhang, Jianqiao, Jiang, Lu-Man, Wang, Luochun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Organophosphonates Water 059QF0KO0R Carbon 7440-44-0 Iron E1UOL152H7
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520 |a Phosphonate is a commonly used corrosion and scale inhibitor for a circulating cooling water (CCW) system. Its discharge could cause eutrophication of receiving waters. The iron-carbon (Fe/C) micro-electrolysis technology was used to degrade and remove phosphonate from discharged CCW. The influences of initial pH, Fe/C ratio (FCR) and temperature on phosphonate removal were investigated in a series of batch tests and optimized by response surface methodology. The quadratic model of phosphonate removal was obtained with satisfactory degrees of fitness. The optimum conditions with total phosphorus removal efficiency of 95% were obtained at pH 7.0, FCR of 1.25, and temperature of 45 °C. The phosphonate removal mechanisms were also studied. Phosphonate removal occurred predominantly via two consecutive reactive phases: the degradation of phosphonate complexes (Ca-phosphonate) and the precipitation of Fe/C micro-electrolysis products (PO₄(3-), Ca²⁺ and Fe³⁺) 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Qiao, Weimin  |e verfasserin  |4 aut 
700 1 |a Lin, Yangbo  |e verfasserin  |4 aut 
700 1 |a Shen, Xuelian  |e verfasserin  |4 aut 
700 1 |a Hu, Dalong  |e verfasserin  |4 aut 
700 1 |a Zhang, Jianqiao  |e verfasserin  |4 aut 
700 1 |a Jiang, Lu-Man  |e verfasserin  |4 aut 
700 1 |a Wang, Luochun  |e verfasserin  |4 aut 
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