Treatment of iron(II)-rich acid mine water with limestone and oxygen

The main components of acid mine water are free acid, sulphate, and Fe²⁺. Limestone is the most cost-effective alkali that can be used for neutralization. The purpose of this investigation was to identify conditions where Fe²⁺ is removed with limestone and simultaneously oxidized with oxygen to Fe³⁺...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 70(2014), 2 vom: 19., Seite 209-17
1. Verfasser: Mohajane, G B (VerfasserIn)
Weitere Verfasser: Maree, J P, Panichev, N
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Industrial Waste Waste Water Water Pollutants, Chemical Iron E1UOL152H7 Calcium Carbonate H0G9379FGK Oxygen S88TT14065
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520 |a The main components of acid mine water are free acid, sulphate, and Fe²⁺. Limestone is the most cost-effective alkali that can be used for neutralization. The purpose of this investigation was to identify conditions where Fe²⁺ is removed with limestone and simultaneously oxidized with oxygen to Fe³⁺, in a polyvinyl chloride pipe under pressure. Gypsum scaling is prevented by passing rubber balls through the pipe of the so-called Oxygen-Pipe-Neutralization (OPeN) process pilot plant. Two synthetic waters were treated: (A) acid mine water containing 123 mg L⁻¹ Fe²⁺ representing gold mine water, and (B) acid mine water containing 6,032 mg L⁻¹ Fe²⁺ representing coal mine water. Batch studies were carried out in a pipe reactor and showed that the rate of Fe²⁺ oxidation depended on the Fe²⁺ concentration, oxygen pressure, amount of recycled sludge, limestone dosage and the mixing rate. Continuous studies in an OPeN process pilot plant resulted in 100% removal of total acidity from synthetic coal mine water and a 98% removal from synthetic gold mine water. Fe²⁺ was removed completely as precipitated Fe(OH)₃ from both synthetic coal and gold mine water at around pH 7 at 200 and 100 kPa oxygen pressure, respectively 
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650 7 |a Industrial Waste  |2 NLM 
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650 7 |a Water Pollutants, Chemical  |2 NLM 
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650 7 |a Calcium Carbonate  |2 NLM 
650 7 |a H0G9379FGK  |2 NLM 
650 7 |a Oxygen  |2 NLM 
650 7 |a S88TT14065  |2 NLM 
700 1 |a Maree, J P  |e verfasserin  |4 aut 
700 1 |a Panichev, N  |e verfasserin  |4 aut 
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