Photoactive films of photosystem I on transparent reduced graphene oxide electrodes

Photosystem I (PSI) is a photoactive electron-transport protein found in plants that participates in the process of photosynthesis. Because of PSI's abundance in nature and its efficiency with charge transfer and separation, there is a great interest in applying the protein in photoactive elect...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 29 vom: 29. Juli, Seite 8990-4
1. Verfasser: Darby, Emily (VerfasserIn)
Weitere Verfasser: LeBlanc, Gabriel, Gizzie, Evan A, Winter, Kevin M, Jennings, G Kane, Cliffel, David E
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Ferricyanides Ferrocyanides Oxides Photosystem I Protein Complex Ruthenium Compounds hexacyanoferrate III 13408-62-3 mehr... hexammineruthenium 19052-44-9 Graphite 7782-42-5 2,6-Dichloroindophenol C35QN2Z58B hexacyanoferrate II FLX0VIC39Y
Beschreibung
Zusammenfassung:Photosystem I (PSI) is a photoactive electron-transport protein found in plants that participates in the process of photosynthesis. Because of PSI's abundance in nature and its efficiency with charge transfer and separation, there is a great interest in applying the protein in photoactive electrodes. Here, we developed a completely organic, transparent, conductive electrode using reduced graphene oxide (RGO) on which a multilayer of PSI could be deposited. The resulting photoactive electrode demonstrated current densities comparable to that of a gold electrode modified with a multilayer film of PSI and significantly higher than that of a graphene electrode modified with a monolayer film of PSI. The relatively large photocurrents produced by integrating PSI with RGO and using an opaque, organic mediator can be applied to the facile production of more economic solar energy conversion devices
Beschreibung:Date Completed 16.10.2015
Date Revised 25.11.2016
published: Print-Electronic
Citation Status MEDLINE
ISSN:1520-5827
DOI:10.1021/la5010616