Thermal dewetting behavior of polystyrene composite thin films with organic-modified inorganic nanoparticles

The thermal dewetting of polystyrene composite thin films with oleic acid-modified CeO2 nanoparticles prepared by the supercritical hydrothermal synthesis method was investigated, varying the nanoparticle concentration (0-30 wt %), film thickness (approximately 50 and 100 nm), and surface energy of...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 29 vom: 29. Juli, Seite 8956-64
1. Verfasser: Kubo, Masaki (VerfasserIn)
Weitere Verfasser: Takahashi, Yosuke, Fujii, Takeshi, Liu, Yang, Sugioka, Ken-ichi, Tsukada, Takao, Minami, Kimitaka, Adschiri, Tadafumi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Thermal dewetting behavior of polystyrene composite thin films with organic-modified inorganic nanoparticles 
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520 |a The thermal dewetting of polystyrene composite thin films with oleic acid-modified CeO2 nanoparticles prepared by the supercritical hydrothermal synthesis method was investigated, varying the nanoparticle concentration (0-30 wt %), film thickness (approximately 50 and 100 nm), and surface energy of silanized silicon substrates on which the composite films were coated. The dewetting behavior of the composite thin films during thermal annealing was observed by an optical microscope. The presence of nanoparticles in the films affected the morphology of dewetting holes, and moreover suppressed the dewetting itself when the concentration was relatively high. It was revealed that there was a critical value of the surface energy of the substrate at which the dewetting occurred. In addition, the spatial distributions of nanoparticles in the composite thin films before thermal annealing were investigated using AFM and TEM. As a result, we found that most of nanoparticles segregated to the surface of the film, and that such distributions of nanoparticles contribute to the stabilization of the films, by calculating the interfacial potential of the films with nanoparticles 
650 4 |a Journal Article 
700 1 |a Takahashi, Yosuke  |e verfasserin  |4 aut 
700 1 |a Fujii, Takeshi  |e verfasserin  |4 aut 
700 1 |a Liu, Yang  |e verfasserin  |4 aut 
700 1 |a Sugioka, Ken-ichi  |e verfasserin  |4 aut 
700 1 |a Tsukada, Takao  |e verfasserin  |4 aut 
700 1 |a Minami, Kimitaka  |e verfasserin  |4 aut 
700 1 |a Adschiri, Tadafumi  |e verfasserin  |4 aut 
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