Functionalization of Complexed N2O in Bis(pentamethylcyclopentadienyl) Systems of Zirconium and Titanium
Methyl triflate reacts with the metastable azoxymetallacyclopentene complex Cp*2Zr(N(O)NCPhCPh), generated in situ from nitrous oxide insertion into the Zr-C bond of Cp*2Zr(η2-PhCCPh) at -78 °C, to afford the salt [Cp*2Zr(N(O)N(Me)CPhCPh)][O3SCF3] (1) in 48% isolated yield. A single-crystal X-ray st...
| Publié dans: | Organometallics. - 1998. - 33(2014), 11 vom: 09. Juni, Seite 2760-2769 |
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| Auteur principal: | |
| Autres auteurs: | , , |
| Format: | Article |
| Langue: | English |
| Publié: |
2014
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| Accès à la collection: | Organometallics |
| Sujets: | Journal Article |