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231224s2014 xx |||||o 00| ||eng c |
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|a 10.1002/mrc.4092
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|a DE-627
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|a eng
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|a Domenici, Valentina
|e verfasserin
|4 aut
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|a Brief overview on 2H NMR studies of polysiloxane-based side-chain nematic elastomers
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|c 2014
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 22.05.2015
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|a Date Revised 25.09.2014
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Copyright © 2014 John Wiley & Sons, Ltd.
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|a This is a brief overview on recent studies on liquid crystalline elastomers (LCEs) based on polysiloxane chain, in the form of monodomain films, selectively (2)H-labeled in different parts of the LCE samples, i.e. on the crosslinker or mesogenic units. (2)H NMR spectroscopic techniques were used to measure the temperature dependence of the quadrupolar splittings, line widths and relaxation times, T(1) and T(2). From these data, several information about the orientational order parameter, S, of various LCE fragments, thermodynamic features of the isotropic-nematic transition and main motional processes could be generalized for this type of elastomers
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|a Journal Article
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|a 2H
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|a NMR
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|a crosslinker
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|a dynamics
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|a liquid crystal elastomer
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|a orientational order
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|a phase transition
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|a Milavec, Jerneja
|e verfasserin
|4 aut
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|a Zupančič, Blaž
|e verfasserin
|4 aut
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|a Bubnov, Alexej
|e verfasserin
|4 aut
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|a Hamplova, Vera
|e verfasserin
|4 aut
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|a Zalar, Boštjan
|e verfasserin
|4 aut
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 52(2014), 10 vom: 21. Okt., Seite 649-55
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|x 1097-458X
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|g volume:52
|g year:2014
|g number:10
|g day:21
|g month:10
|g pages:649-55
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|u http://dx.doi.org/10.1002/mrc.4092
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