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231224s2014 xx |||||o 00| ||eng c |
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|a 10.1021/la5011727
|2 doi
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|a eng
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1 |
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|a Adamkiewicz, Malgorzata
|e verfasserin
|4 aut
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|a Bis(trifluoromethyl)methylene addition to vinyl-terminated SAMs
|b a gas-phase C-C bond-forming reaction on a surface
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|c 2014
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 15.04.2015
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|a Date Revised 21.10.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Vinyl-terminated self-assembled monolayers (SAMs) on silicon oxide substrates were chemically modified by the addition of a bis(trifluoromethyl)methylene group in a rare gas-phase C-C bond-forming reaction to directly generate films carrying terminal CF3 groups. The vinyl-terminated films were treated with hexafluoroacetone azine (HFAA) for modification. The films were characterized with ellipsometry, contact angle measurements, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). In this study, we find that for optimized conditions clean reactions occur on a surface between SAMs with terminal olefins and HFAA, and the product is consistent with bis(trifluoromethyl)cyclopropanation formation after nitrogen extrusion
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|a Journal Article
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|a O'Hagan, David
|e verfasserin
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|a Hähner, Georg
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 30(2014), 19 vom: 20. Mai, Seite 5422-8
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|x 1520-5827
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|g volume:30
|g year:2014
|g number:19
|g day:20
|g month:05
|g pages:5422-8
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