Synchrotron far-infrared spectroscopy of corroded steel surfaces using a variable angle of incidence
Far-infrared spectroscopy, using a synchrotron source, has been used to study carbon steel corroded in CO2-saturated brine in the presence and absence of the corrosion inhibitor 2-mercaptopyrimidine (MPY), which allowed the steel surface roughness to be modified. The effect of the angle of incidence...
| Veröffentlicht in: | Journal of synchrotron radiation. - 1994. - 21(2014), Pt 3 vom: 01. Mai, Seite 580-5 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2014
|
| Zugriff auf das übergeordnete Werk: | Journal of synchrotron radiation |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't absorption intensity corrosion corrosion inhibitor far-infrared spectroscopy incidence angle surface roughness |
| Zusammenfassung: | Far-infrared spectroscopy, using a synchrotron source, has been used to study carbon steel corroded in CO2-saturated brine in the presence and absence of the corrosion inhibitor 2-mercaptopyrimidine (MPY), which allowed the steel surface roughness to be modified. The effect of the angle of incidence (θi, 30-80°) on the band intensity and observed bands of the spectra from these surfaces has been determined. For the MPY-treated steel (low surface roughness) the highest band intensity is observed at high θi (80°) and different bands were observed at different θi. In contrast, for the MPY-free steel (high surface roughness) the highest band intensity is observed at low θi (30°) and spectral content changes were not observed. The results are explained in terms of the roughness of the MPY-treated and MPY-free steels, and their effect on the level of diffusely reflected light of the incident infrared beam |
|---|---|
| Beschreibung: | Date Completed 30.03.2015 Date Revised 25.04.2014 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1600-5775 |
| DOI: | 10.1107/S1600577514004159 |