Bioinspired Hydrogenase Models The Mixed-Valence Triiron Complex [Fe3(CO)7(μ-edt)2] and Phosphine Derivatives [Fe3(CO)7-x (PPh3) x (μ-edt)2] (x = 1, 2) and [Fe3(CO)5(κ2-diphosphine)(μ-edt)2] as Proton Reduction Catalysts

Bioinspired Hydrogenase Models : The Mixed-Valence Triiron Complex [Fe3(CO)7(μ-edt)2] and Phosphine Derivatives [Fe3(CO)7-x (PPh3) x (μ-edt)2] (x = 1, 2) and [Fe3(CO)5(κ2-diphosphine)(μ-edt)2] as Proton Reduction Catalysts

The mixed-valence triiron complexes [Fe3(CO)7-x (PPh3) x (μ-edt)2] (x = 0-2; edt = SCH2CH2S) and [Fe3(CO)5(κ2-diphosphine)(μ-edt)2] (diphosphine = dppv, dppe, dppb, dppn) have been prepared and structurally characterized. All adopt an anti arrangement of the dithiolate bridges, and PPh3 substitution...

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Veröffentlicht in:Organometallics. - 1998. - 33(2014), 6 vom: 24. März, Seite 1356-1366
1. Verfasser: Rahaman, Ahibur (VerfasserIn)
Weitere Verfasser: Ghosh, Shishir, Unwin, David G, Basak-Modi, Sucharita, Holt, Katherine B, Kabir, Shariff E, Nordlander, Ebbe, Richmond, Michael G, Hogarth, Graeme
Format: Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Organometallics
Schlagworte:Journal Article