Stoichiometry-driven switching between surface reconstructions on SrTiO3(001)

Controlling the surface structure on the atomic scale is a major difficulty for most transition metal oxides; this is especially true for the ternary perovskites. The influence of surface stoichiometry on the atomic structure of the SrTiO3(001) surface was examined with scanning tunneling microscopy...

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Veröffentlicht in:Surface science. - 1997. - 621(2014), 100 vom: 16. März, Seite L1-L4
1. Verfasser: Gerhold, Stefan (VerfasserIn)
Weitere Verfasser: Wang, Zhiming, Schmid, Michael, Diebold, Ulrike
Format: Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Surface science
Schlagworte:Journal Article Low energy electron diffraction Low energy ion scattering Scanning tunneling microscopy Strontium titanate Surface stoichiometry X-ray photoelectron spectroscopy
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520 |a Controlling the surface structure on the atomic scale is a major difficulty for most transition metal oxides; this is especially true for the ternary perovskites. The influence of surface stoichiometry on the atomic structure of the SrTiO3(001) surface was examined with scanning tunneling microscopy, low-energy electron diffraction, low-energy He+ ion scattering (LEIS), and X-ray photoelectron spectroscopy (XPS). Vapor deposition of 0.8 monolayer (ML) strontium and 0.3 ML titanium, with subsequent annealing to 850 °C in 4 × 10- 6 mbar O2, reversibly switches the surface between c(4 × 2) and (2 × 2) reconstructions, respectively. The combination of LEIS and XPS shows a different stoichiometry that is confined to the top layer. Geometric models for these reconstructions need to take into account these different surface compositions 
650 4 |a Journal Article 
650 4 |a Low energy electron diffraction 
650 4 |a Low energy ion scattering 
650 4 |a Scanning tunneling microscopy 
650 4 |a Strontium titanate 
650 4 |a Surface stoichiometry 
650 4 |a X-ray photoelectron spectroscopy 
700 1 |a Wang, Zhiming  |e verfasserin  |4 aut 
700 1 |a Schmid, Michael  |e verfasserin  |4 aut 
700 1 |a Diebold, Ulrike  |e verfasserin  |4 aut 
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