Preparation and catalytic activity of Pd and bimetallic Pd-Ni nanowires

This article describes the preparation and catalytic property of Pd and Pd-Ni nanowires with network structure. A soft template with network structure formed by long-chain amidoamine derivative (C18AA) was essential to preparing Pd and Pd-Ni nanowires because of the preparation of only spherical nan...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 17 vom: 06. Mai, Seite 5026-30
1. Verfasser: Imura, Yoshiro (VerfasserIn)
Weitere Verfasser: Tsujimoto, Katsura, Morita, Clara, Kawai, Takeshi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
Beschreibung
Zusammenfassung:This article describes the preparation and catalytic property of Pd and Pd-Ni nanowires with network structure. A soft template with network structure formed by long-chain amidoamine derivative (C18AA) was essential to preparing Pd and Pd-Ni nanowires because of the preparation of only spherical nanoparticles using octadecylamine, which does not form a network structure as a soft template, instead of C18AA. Furthermore, this soft-template method demands a slow reduction rate for the metal ion, the same as the general preparation method for novel metal nanowires. The distinguishing features of the present method is that the nanowires are a few nanometers in diameter and there are no byproducts such as nanoparticles. In addition, the bimetallic Pd-Ni nanowires show very high catalytic activity for the hydrogenation of p-nitrophenol as compared to Pd nanowires, Pd nanoparticles, and Pd-Ni nanoparticles
Beschreibung:Date Completed 15.04.2015
Date Revised 06.05.2014
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827
DOI:10.1021/la500811n