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231224s2014 xx |||||o 00| ||eng c |
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|a 10.1021/la500127n
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|a eng
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|a Nguyen, Khanh Thuy
|e verfasserin
|4 aut
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|a Self-assembly-driven nematization
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|c 2014
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 15.04.2015
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|a Date Revised 29.04.2014
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The anisotropy of attractive interactions between particles can favor, through a self-assembly process, the formation of linear semi-flexible chains. In the appropriate temperatures and concentration ranges, the growing aspect ratio of the aggregates can induce formation of a nematic phase, as recently experimentally observed in several biologically relevant systems. We present here a numerical study of the isotropic-nematic phase boundary for a model of bifunctional polymerizing hard cylinders, to provide an accurate benchmark for recent theoretical approaches and to assess their ability to capture the coupling between self-assembly and orientational ordering. The comparison indicates the importance of properly modeling excluded volume and orientational entropy and provides a quantitative confirmation of some theoretical predictions
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|a Journal Article
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|a Sciortino, Francesco
|e verfasserin
|4 aut
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|a De Michele, Cristiano
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 30(2014), 16 vom: 29. Apr., Seite 4814-9
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|x 1520-5827
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|g volume:30
|g year:2014
|g number:16
|g day:29
|g month:04
|g pages:4814-9
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|u http://dx.doi.org/10.1021/la500127n
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