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231224s2014 xx |||||o 00| ||eng c |
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|a 10.1021/la5000588
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|a eng
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| 100 |
1 |
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|a Davis, Andrew R
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Surface grafting of vinyl-functionalized poly(fluorene)s via thiol-ene click chemistry
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| 264 |
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|c 2014
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 15.04.2015
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|a Date Revised 23.04.2014
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Thiol-ene chemistry is used for the surface grafting of vinyl-functionalized poly(fluorene) derivatives onto substrates containing free surface thiol groups. The grafting reaction proceeds in a matter of minutes under UV irradiation without photoinitiator, and the resulting surface-bound, solvent-impervious conjugated polymers retain their characteristic optoelectronic properties. End-chain grafted poly(fluorene)s reach greater surface densities than their side-chain grafted counterparts and show less blue-shifting of photoluminescence upon grafting, suggesting that chain end-grafted conjugated polymers experience less disruption of their extended conjugation and adopt a more brush-like surface conformation. Surface grafted poly(fluorene)s showed facile photopatterning, and thin film transistors with semiconducting polymers directly grafted to the dielectric layer showed performances directly comparable to conventional self-assembled layers of performance-improving alkylsilanes
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|a Journal Article
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|a Carter, Kenneth R
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
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|g 30(2014), 15 vom: 22. Apr., Seite 4427-33
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|g year:2014
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|g day:22
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|u http://dx.doi.org/10.1021/la5000588
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