Selective dopamine chemosensing using silver-enhanced fluorescence

Condensation product of salicylaldehyde and 1,3 propylenediamine becomes a diiminic Schiff base, which is oxidized by AgNO3 in alkaline solution, and in turn, stable Ag(0) is produced at room temperature. Under this condition, the solution exhibits intense silver nanoparticle enhanced fluorescence (...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 14 vom: 15. Apr., Seite 4120-8
1. Verfasser: Ganguly, Mainak (VerfasserIn)
Weitere Verfasser: Mondal, Chanchal, Jana, Jayasmita, Pal, Anjali, Pal, Tarasankar
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Fluorescent Dyes Ions Silver 3M4G523W1G Mercury FXS1BY2PGL Dopamine VTD58H1Z2X
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520 |a Condensation product of salicylaldehyde and 1,3 propylenediamine becomes a diiminic Schiff base, which is oxidized by AgNO3 in alkaline solution, and in turn, stable Ag(0) is produced at room temperature. Under this condition, the solution exhibits intense silver nanoparticle enhanced fluorescence (SEF) with the λ(em) at 412 nm. Dopamine is selectively detected down to the nanomolar level via exclusive fluorescence quenching of the SEF. Dopamine-infested solution regains the fluorescence [i.e., SEF in the presence of Hg(II) ions]. Thus dopamine and Hg(II) in succession demonstrate "turn off/on" fluorescence due to the change in the scattering cross section of Ag(0) and gives a quantitative measure of dopamine in real samples. The proposed method is free from interferences of common biocompetitors 
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700 1 |a Pal, Tarasankar  |e verfasserin  |4 aut 
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