Triptycene induced enhancement of membrane gas selectivity for microporous Tröger's base polymers
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 26(2014), 21 vom: 04. Juni, Seite 3526-31 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2014
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article Research Support, Non-U.S. Gov't gas separation intrinsic microporosity polymer membranes triptycene |
Zusammenfassung: | © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A highly gas permeable polymer with exceptional size selectivity is prepared by fusing triptycene units together via a poly-merization reaction involving Tröger's base formation. The extreme rigidity of this polymer of intrinsic microporosity (PIM-Trip-TB) facilitates gas permeability data that lie well above the benchmark 2008 Robeson upper bounds for the important O2 /N2 and H2 /N2 gas pairs |
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Beschreibung: | Date Completed 11.05.2015 Date Revised 22.03.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201305783 |