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231224s2014 xx |||||o 00| ||eng c |
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|a 10.1021/la500646r
|2 doi
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|a pubmed25n0787.xml
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|a DE-627
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|e rakwb
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|a eng
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|a Tan, Tristan Tsai Yuan
|e verfasserin
|4 aut
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|a Photoresponsive liquid marbles and dry water
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|c 2014
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 25.11.2014
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|a Date Revised 01.04.2014
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Stimuli-responsive liquid marbles for controlled release typically rely on organic moieties that require lengthy syntheses. We report herein a facile, one-step synthesis of hydrophobic and oleophobic TiO2 nanoparticles that display photoresponsive wettability. Water liquid marbles stabilized by these photoresponsive TiO2 particles were found to be stable when shielded from ultraviolet (UV) radiation; however, they quickly collapsed after being irradiated with 302 nm UV light. Oil- and organic-solvent-based liquid marbles could also be fabricated using oleophobic TiO2 nanoparticles and show similar UV-induced collapse. Finally, we demonstrated the formation of the micronized form of water liquid marbles, also known as dry water, by homogenization of the TiO2 nanoparticles with water. The TiO2 dry water displayed a similar photoresponse, whereby the micronized liquid marbles collapsed after irradiation and the dry water turned from a free-flowing powder to a paste. Hence, by exploiting the photoresponsive wettability of TiO2, we fabricated liquid marbles and dry water that display photoresponse and studied the conditions required for their collapse
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Oils
|2 NLM
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|a Solvents
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|a Water
|2 NLM
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|a 059QF0KO0R
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|a titanium dioxide
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|a Titanium
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|a Ahsan, Aniq
|e verfasserin
|4 aut
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|a Reithofer, Michael R
|e verfasserin
|4 aut
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|a Tay, Siok Wei
|e verfasserin
|4 aut
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|a Tan, Sze Yu
|e verfasserin
|4 aut
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|a Hor, Tzi Sum Andy
|e verfasserin
|4 aut
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|a Chin, Jia Min
|e verfasserin
|4 aut
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|a Chew, Benny Kia Jia
|e verfasserin
|4 aut
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|a Wang, Xiaobai
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 30(2014), 12 vom: 01. Apr., Seite 3448-54
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:30
|g year:2014
|g number:12
|g day:01
|g month:04
|g pages:3448-54
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|u http://dx.doi.org/10.1021/la500646r
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