Photoresponsive liquid marbles and dry water

Stimuli-responsive liquid marbles for controlled release typically rely on organic moieties that require lengthy syntheses. We report herein a facile, one-step synthesis of hydrophobic and oleophobic TiO2 nanoparticles that display photoresponsive wettability. Water liquid marbles stabilized by thes...

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Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 30(2014), 12 vom: 01. Apr., Seite 3448-54
Auteur principal: Tan, Tristan Tsai Yuan (Auteur)
Autres auteurs: Ahsan, Aniq, Reithofer, Michael R, Tay, Siok Wei, Tan, Sze Yu, Hor, Tzi Sum Andy, Chin, Jia Min, Chew, Benny Kia Jia, Wang, Xiaobai
Format: Article en ligne
Langue:English
Publié: 2014
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article Research Support, Non-U.S. Gov't Oils Solvents Water 059QF0KO0R titanium dioxide 15FIX9V2JP Titanium D1JT611TNE
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520 |a Stimuli-responsive liquid marbles for controlled release typically rely on organic moieties that require lengthy syntheses. We report herein a facile, one-step synthesis of hydrophobic and oleophobic TiO2 nanoparticles that display photoresponsive wettability. Water liquid marbles stabilized by these photoresponsive TiO2 particles were found to be stable when shielded from ultraviolet (UV) radiation; however, they quickly collapsed after being irradiated with 302 nm UV light. Oil- and organic-solvent-based liquid marbles could also be fabricated using oleophobic TiO2 nanoparticles and show similar UV-induced collapse. Finally, we demonstrated the formation of the micronized form of water liquid marbles, also known as dry water, by homogenization of the TiO2 nanoparticles with water. The TiO2 dry water displayed a similar photoresponse, whereby the micronized liquid marbles collapsed after irradiation and the dry water turned from a free-flowing powder to a paste. Hence, by exploiting the photoresponsive wettability of TiO2, we fabricated liquid marbles and dry water that display photoresponse and studied the conditions required for their collapse 
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700 1 |a Ahsan, Aniq  |e verfasserin  |4 aut 
700 1 |a Reithofer, Michael R  |e verfasserin  |4 aut 
700 1 |a Tay, Siok Wei  |e verfasserin  |4 aut 
700 1 |a Tan, Sze Yu  |e verfasserin  |4 aut 
700 1 |a Hor, Tzi Sum Andy  |e verfasserin  |4 aut 
700 1 |a Chin, Jia Min  |e verfasserin  |4 aut 
700 1 |a Chew, Benny Kia Jia  |e verfasserin  |4 aut 
700 1 |a Wang, Xiaobai  |e verfasserin  |4 aut 
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