Photo-Fenton degradation of phenol, 2,4-dichlorophenoxyacetic acid and 2,4-dichlorophenol mixture in saline solution using a falling-film solar reactor

In this work, a saline aqueous solution of phenol, 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4-dichlorophenol (2,4-DCP) was treated by the photo-Fenton process in a falling-film solar reactor. The influence of the parameters such as initial pH (5-7), initial concentration of Fe2+ (1-2.5mM) and ra...

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Veröffentlicht in:Environmental technology. - 1993. - 35(2014), 1-4 vom: 28. Jan., Seite 364-71
1. Verfasser: Luna, Airton J (VerfasserIn)
Weitere Verfasser: Nascimento, Cláudio A O, Foletto, Edson Luiz, Moraes, José E F, Chiavone-Filhoe, Osvaldo
Format: Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Complex Mixtures Fenton's reagent Phenols 2,4-Dichlorophenoxyacetic Acid 2577AQ9262 Sodium Chloride 451W47IQ8X Hydrogen Peroxide mehr... BBX060AN9V Iron E1UOL152H7
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245 1 0 |a Photo-Fenton degradation of phenol, 2,4-dichlorophenoxyacetic acid and 2,4-dichlorophenol mixture in saline solution using a falling-film solar reactor 
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520 |a In this work, a saline aqueous solution of phenol, 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4-dichlorophenol (2,4-DCP) was treated by the photo-Fenton process in a falling-film solar reactor. The influence of the parameters such as initial pH (5-7), initial concentration of Fe2+ (1-2.5mM) and rate of H202 addition (1.87-3.74mmol min-1) was investigated. The efficiency of photodegradation was determined from the removal of dissolved organic carbon (DOC), described by the species degradation of phenol, 2,4-D and 2,4-DCP. Response surface methodology was employed to assess the effects of the variables investigated, i.e. [Fe2+], [H202] and pH, in the photo-Fenton process with solar irradiation. The results reveal that the variables' initial concentration of Fe2+ and H202 presents predominant effect on pollutants' degradation in terms of DOC removal, while pH showed no influence. Under the most adequate experimental conditions, about 85% DOC removal was obtained in 180 min by using a reaction system employed here, and total removal of phenol, 2,4- and 2,4-DCP mixture in about 30min 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a 2,4-Dichlorophenoxyacetic Acid  |2 NLM 
650 7 |a 2577AQ9262  |2 NLM 
650 7 |a Sodium Chloride  |2 NLM 
650 7 |a 451W47IQ8X  |2 NLM 
650 7 |a Hydrogen Peroxide  |2 NLM 
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650 7 |a Iron  |2 NLM 
650 7 |a E1UOL152H7  |2 NLM 
700 1 |a Nascimento, Cláudio A O  |e verfasserin  |4 aut 
700 1 |a Foletto, Edson Luiz  |e verfasserin  |4 aut 
700 1 |a Moraes, José E F  |e verfasserin  |4 aut 
700 1 |a Chiavone-Filhoe, Osvaldo  |e verfasserin  |4 aut 
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