Enhanced infrared LSPR sensitivity of cap-shaped gold nanoparticles coupled to a metallic film
We report on optical properties of gold deposited on SiO2 nanospheres randomly adsorbed on a thin gold layer. Extinction peaks with optical density of more than 2 are observed in the visible as well as near-IR regimes. The peak wavelength of the latter was affected exquisitely by the thickness of th...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1999. - 30(2014), 8 vom: 04. März, Seite 2297-305 |
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| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | We report on optical properties of gold deposited on SiO2 nanospheres randomly adsorbed on a thin gold layer. Extinction peaks with optical density of more than 2 are observed in the visible as well as near-IR regimes. The peak wavelength of the latter was affected exquisitely by the thickness of the top layer. A helium ion microscope (HIM) was used for careful observation of morphological transformation accompanying the change in the deposition thickness. Growth of grain structures into a capped-dimer structure was accompanied by slight blue-shift of the visible peak and significantly greater red-shift of the near-IR peak. Our finite-difference time-domain (FDTD) calculations show that these peaks in the visible and near-IR can be respectively attributed to dipole modes associated with transverse and longitudinal oscillations of free electrons in the gold-capped dimer. To investigate the refractive index sensitivity of these peaks, we used two approaches: immersion in solutions of varying refractive index and coating with an organic layer. With the first approach that characterizes the bulk sensitivity, the visible peak shows sensitivity of 122 nm/RIU, while the near-IR peak shifts at the rate of 506 nm/RIU. With the second approach that reflects the local sensitivity, the surface was saturated with alkaline phosphatase (ALP), whose subsequent reaction led to formation of a thin insoluble organic layer, causing a relatively small blue-shift, under 7 nm, of the visible peak and much larger red-shift, over 50 nm, of the near-IR peak when measured in buffer. When the same reaction was measured at end points in the air, the shift was as large as 444 nm for the near-IR peak |
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| Beschreibung: | Date Completed 20.10.2014 Date Revised 05.03.2014 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la403407g |