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231224s2014 xx |||||o 00| ||eng c |
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|a 10.1021/la404569h
|2 doi
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|a eng
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|a Lista, Marco
|e verfasserin
|4 aut
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|a Phase transfer of noble metal nanoparticles to organic solvents
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|c 2014
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|a Text
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|a Date Completed 20.10.2014
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|a Date Revised 05.03.2014
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Nanoparticles are finding increasing application because of their unusual optical properties. Processing these materials would be drastically simplified if they could be routinely dispersed into a wide variety of polar and nonpolar solvents. We report the synthesis of a new bidentate thiol ligand, (Z)-octadec-9-en-1-yl-5-(1,2-dithiolan-3-yl)pentanoate, and demonstrate its ability to phase transfer gold nanospheres (5-70 nm), nanorods, and silver nanoparticles efficiently from water into various organic solvents. The protocol obviates the need for solid-phase steps or polymeric ligands. Electronic spectra and electron micrographs demonstrate that the particles are fully dispersed in a variety of organic solvents after transfer
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|a Journal Article
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|a Gold
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|a Liu, Dylan Zhe
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|a Mulvaney, Paul
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|t Langmuir : the ACS journal of surfaces and colloids
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