Overgrowth of gold nanorods by using a binary surfactant mixture

Seed-mediated surfactant-assisted growth is widely used as the most effective method for gold nanorod (NR) synthesis. Using prepared nanorods as seeds for further overgrowth can increase the dimensional tunability of the final particles. However, overgrowth in usual cetyltrimethylammonium bromide (C...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 6 vom: 18. Feb., Seite 1696-703
1. Verfasser: Khlebtsov, Boris N (VerfasserIn)
Weitere Verfasser: Khanadeev, Vitaly A, Ye, Jian, Sukhorukov, Gleb B, Khlebtsov, Nikolai G
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Cetrimonium Compounds Surface-Active Agents Oleic Acid 2UMI9U37CP osteum 399SL044HN Gold 7440-57-5 mehr... Cetrimonium Z7FF1XKL7A
Beschreibung
Zusammenfassung:Seed-mediated surfactant-assisted growth is widely used as the most effective method for gold nanorod (NR) synthesis. Using prepared nanorods as seeds for further overgrowth can increase the dimensional tunability of the final particles. However, overgrowth in usual cetyltrimethylammonium bromide (CTAB) surfactant solutions leads to poor control of the final particle shape and size. In this work, we report an improved strategy to demonstrate the controllable overgrowth of gold NRs in the binary surfactant mixture sodium oleate (NaOL) + CTAB. This approach overcomes the difficulty of growing NR suspensions with small amounts of impurities. By controlling the total amount of added NR seeds, it is possible to tune the average length, diameter, and plasmon resonances of overgrown particles in a wide range. Together with the original NaOL + CTAB method developed by Murray and co-workers ( Nano Lett. 2013 , 13 , 555 ), this overgrowth approach expands the dimensional and plasmonic tunability of the fabrication technology without any decrease in the monodispersity and purity of samples
Beschreibung:Date Completed 06.10.2014
Date Revised 02.12.2018
published: Print-Electronic
Citation Status MEDLINE
ISSN:1520-5827
DOI:10.1021/la404399n