|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM23477410X |
| 003 |
DE-627 |
| 005 |
20231224102001.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2014 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la404826k
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0782.xml
|
| 035 |
|
|
|a (DE-627)NLM23477410X
|
| 035 |
|
|
|a (NLM)24455981
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Li, Qintang
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Phase transition of a quaternary ammonium Gemini surfactant induced by minor structural changes of protic ionic liquids
|
| 264 |
|
1 |
|c 2014
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 06.10.2014
|
| 500 |
|
|
|a Date Revised 18.02.2014
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a The aggregation behaviors of a Gemini surfactant [C12H25(CH3)2N(+)(CH2)2N(+)(CH3)2C12H25]Br2(-) (12-2-12) in two protic ionic liquids (PILs), propylammonium nitrate (PAN) and butylammonium nitrate (BAN), were investigated by means of several experimental techniques including small and wide-angle X-ray scattering, the polarized optical microscopy and the rheological measurement. Compared to those in ethylammonium nitrate (EAN), the minor structural changes with only one or two methylene units (-CH2-) increase in cationic chain length of PIL, result in a dramatic phase transition of formed aggregates. The critical micellization concentration was increased in PAN, while no micelle formation was detected in BAN. A normal hexagonal phase was observed in the 12-2-12/PAN system, while the normal hexagonal, bicontinuous cubic, and lamellar phases were mapped in the 12-2-12/BAN system. Such aggregation behavior changes can be ascribed to the weaker solvophobic interactions of 12-2-12 in PAN and BAN. The unique molecular structure of 12-2-12 is also an important factor to highlight such a dramatic phase transition due to the PIL structure change
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Wang, Xudong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yue, Xiu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Xiao
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 30(2014), 6 vom: 18. Feb., Seite 1522-30
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:30
|g year:2014
|g number:6
|g day:18
|g month:02
|g pages:1522-30
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la404826k
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 30
|j 2014
|e 6
|b 18
|c 02
|h 1522-30
|