Templating fullerenes by domain boundaries of a nanoporous network
We present a new templating approach that combines the templating properties of nanoporous networks with the dynamic properties and the lattice mismatch of domain boundaries. This templating approach allows for the inclusion of guests with different sizes without the need for a strict molecular desi...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 3 vom: 28. Jan., Seite 762-7 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2014
|
| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Fullerenes |
| Zusammenfassung: | We present a new templating approach that combines the templating properties of nanoporous networks with the dynamic properties and the lattice mismatch of domain boundaries. This templating approach allows for the inclusion of guests with different sizes without the need for a strict molecular design to tailor the nanoporous network. With this approach, nonperiodic patterns of functional molecules can be formed and studied. We show that domain boundaries in a trimesic acid network are preferred over pores within the network as adsorption sites for fullerenes by a factor of 100-200. Pristine fullerenes of different sizes and functionalized fullerenes were templated in this way |
|---|---|
| Beschreibung: | Date Completed 03.09.2014 Date Revised 26.01.2018 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la403807x |