Guest-cage atomic interactions in a clathrate-based phase-change material

© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 26(2014), 11 vom: 19. März, Seite 1725-30
1. Verfasser: Loke, Desmond (VerfasserIn)
Weitere Verfasser: Skelton, Jonathan M, Law, Leong-Tat, Wang, Wei-Jie, Li, Ming-Hua, Song, Wen-Dong, Lee, Tae-Hoon, Elliott, Stephen R
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Research Support, Non-U.S. Gov't clathrate compounds crystallization kinetics guest-cage interactions nano-engineering phase-change materials
Beschreibung
Zusammenfassung:© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
New clathrate-based phase-change materials with cage-like structures incorporating Cs and Ba guest atoms, are reported as a means of altering crystallization and amorphization behavior by controlling 'guest-cage' interactions via intra-complex guest vibrational effects. Both a high resistance to spontaneous crystallization, and long retention of the amorphous phase are achieved, as well as a low melting energy. This approach provides a route for achieving cage-controlled semiconductor devices
Beschreibung:Date Completed 24.11.2014
Date Revised 30.09.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201304199