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231224s2014 xx |||||o 00| ||eng c |
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|a 10.1107/S1600577513028786
|2 doi
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|a pubmed25n0779.xml
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|a (DE-627)NLM233924213
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|a (NLM)24365945
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|a DE-627
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|a eng
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|a Boita, Jocenir
|e verfasserin
|4 aut
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|a A reaction cell for time-resolved in situ XAS studies during wet chemical synthesis
|b the Cu2(OH)3Cl case
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|c 2014
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 15.08.2014
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|a Date Revised 24.12.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The use of in situ time-resolved dispersive X-ray absorption spectroscopy (DXAS) to monitor the formation of Cu2(OH)3Cl particles in an aqueous solution is reported. The measurements were performed using a dedicated reaction cell, which enabled the evolution of the Cu K-edge X-ray absorption near-edge spectroscopy to be followed during mild chemical synthesis. The formed Cu2(OH)3Cl particles were also characterized by synchrotron-radiation-excited X-ray photoelectron spectroscopy, X-ray diffraction and scanning electron microscopy. The influence of polyvinylpyrrolidone (PVP) on the electronic and structural properties of the formed particles was investigated. The results indicate clearly the formation of Cu2(OH)3Cl, with or without the use of PVP, which presents very similar crystalline structures in the long-range order. However, depending on the reaction, dramatic differences were observed by in situ DXAS in the vicinities of the Cu atoms
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|a Journal Article
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|a Cu2(OH)3Cl
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|a DXAS
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|a X-ray absorption
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|a copper
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|a in situ
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|a Alves, Maria do Carmo Martins
|e verfasserin
|4 aut
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|a Morais, Jonder
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Journal of synchrotron radiation
|d 1994
|g 21(2014), Pt 1 vom: 15. Jan., Seite 254-8
|w (DE-627)NLM09824129X
|x 1600-5775
|7 nnns
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| 773 |
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|g volume:21
|g year:2014
|g number:Pt 1
|g day:15
|g month:01
|g pages:254-8
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|u http://dx.doi.org/10.1107/S1600577513028786
|3 Volltext
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|d 21
|j 2014
|e Pt 1
|b 15
|c 01
|h 254-8
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