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231224s2013 xx |||||o 00| ||eng c |
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|a 10.2166/wst.2013.557
|2 doi
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|a pubmed24n0779.xml
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|a (NLM)24355861
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Liu, Yu
|e verfasserin
|4 aut
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|a Removal of PCP-Na from aqueous systems using monodispersed pompon-like magnetic nanoparticles as adsorbents
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 13.03.2014
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|a Date Revised 20.12.2013
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|a published: Print
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|a Citation Status MEDLINE
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|a Novel monodispersed pompon-like magnetite/chitosan (Fe3O4/CS) composite nanoparticles were synthesized by a solvothermal method and used as adsorbents for the removal of toxic sodium pentachlorophenate (PCP-Na) from aqueous media. The adsorption behavior of PCP-Na on Fe3O4/CS obeyed the Langmuir isotherm and fitted the pseudo-second-order kinetics model. Thermodynamic parameters showed that the adsorption process was exothermic and spontaneous. Moreover, the adsorption was strongly pH-dependent. The results of XPS, thermodynamics, pH-dependent and desorption studies suggested that electrostatic attraction, hydrogen bonding and π-π interactions were all believed to play a role in PCP-Na adsorption on Fe3O4/CS. Having a saturation magnetization of 22.2 emu · g(-1), the Fe3O4/CS can be easily separated from water with magnets within 2 min. The adsorption equilibrium was achieved quite rapidly (within 30 min) and the maximum removal of PCP-Na (91.5%) was obtained at 25 °C and pH 6.5. The Fe3O4/CS investigated can be used to remove PCP-Na and other contaminants from wastewater
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Magnetite Nanoparticles
|2 NLM
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|a Water Pollutants, Chemical
|2 NLM
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|a Chitosan
|2 NLM
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|a 9012-76-4
|2 NLM
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|a Pentachlorophenol
|2 NLM
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|a D9BSU0SE4T
|2 NLM
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|a Yu, Hongbing
|e verfasserin
|4 aut
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|a Zhan, Sihui
|e verfasserin
|4 aut
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1 |
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|a Li, Shengjun
|e verfasserin
|4 aut
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|a Yang, Hui
|e verfasserin
|4 aut
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|a Liu, Bo
|e verfasserin
|4 aut
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|i Enthalten in
|t Water science and technology : a journal of the International Association on Water Pollution Research
|d 1986
|g 68(2013), 12 vom: 19., Seite 2704-11
|w (DE-627)NLM098149431
|x 0273-1223
|7 nnns
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|g volume:68
|g year:2013
|g number:12
|g day:19
|g pages:2704-11
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|u http://dx.doi.org/10.2166/wst.2013.557
|3 Volltext
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