Confinement of water in hydrophobic nanopores : effect of the geometry on the energy of intrusion

Water confinement in the hydrophobic nanopores of highly siliceous zeolite having MFI and CHA topology is investigated by high pressure manometry coupled to differential calorimetry. Surprisingly, the intrusion of water is endothermic for MFI but exothermic for CHA. This phase transition depends on...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 30(2014), 1 vom: 14. Jan., Seite 213-9
1. Verfasser: Karbowiak, Thomas (VerfasserIn)
Weitere Verfasser: Weber, Guy, Bellat, Jean-Pierre
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article