Advanced oxidation of hypophosphite and phosphite using a UV/H2O2 process

The oxidation of hypophosphite and phosphite in an aqueous solution by an ultraviolet (UV)/H2O2 process was studied in this work. The reactions were performed in a lab-scale batch photoreactor. The effect of different parameters such as H2O2 dosage, H2O2 feeding mode and the initial pH of the soluti...

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Veröffentlicht in:Environmental technology. - 1998. - 34(2013), 13-16 vom: 17. Juli, Seite 2231-9
1. Verfasser: Liu, Peng (VerfasserIn)
Weitere Verfasser: Li, Chaolin, Liang, Xingang, Xu, Jianhui, Lu, Gang, Ji, Fei
Format: Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Phosphites Waste Water Hydrogen Peroxide BBX060AN9V
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520 |a The oxidation of hypophosphite and phosphite in an aqueous solution by an ultraviolet (UV)/H2O2 process was studied in this work. The reactions were performed in a lab-scale batch photoreactor. The effect of different parameters such as H2O2 dosage, H2O2 feeding mode and the initial pH of the solution on the oxidation efficiency of the process was investigated. The results indicated that the UV/H2O2 process could effectively oxidize hypophosphite and phosphite in both synthesized and real wastewater. However, neither H2O2 nor UV alone was able to appreciably oxidize the hypophosphite or phosphite. The best way of feeding H2O2 was found to be 'continuous feeding', which maximized the reaction rate. It was also found that the process presented a wide range of applicable initial pH (5-11). When treating real rinse-wastewater, which was obtained from the electroless nickel plating industry, both hypophosphite and phosphite were completely oxidized within 60 min, and by extending by another 30 min, over 90% of the chemical oxygen demand removal was obtained. Without any additional catalyst, the UV/H2O2 process can oxidize hypophosphite and phosphite to easily removable phosphate. It is really a powerful and environmentally friendly treatment method for the wastewater containing hypophosphite and phosphite 
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700 1 |a Li, Chaolin  |e verfasserin  |4 aut 
700 1 |a Liang, Xingang  |e verfasserin  |4 aut 
700 1 |a Xu, Jianhui  |e verfasserin  |4 aut 
700 1 |a Lu, Gang  |e verfasserin  |4 aut 
700 1 |a Ji, Fei  |e verfasserin  |4 aut 
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