Multifunctional silicon surfaces : reaction of dichlorocarbene generated from Seyferth reagent with hydrogen-terminated silicon (111) surfaces

Insertion of dichlorocarbene (:CCl2), generated by decomposition of the Seyferth reagent PhHgCCl2Br, into the Si-H bond of a tertiary silane to form a Si-CCl2H group is an efficient homogeneous, molecular transformation. A heterogeneous version of this reaction, between PhHgCCl2Br and a silicon (111...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 1 vom: 14. Jan., Seite 172-8
1. Verfasser: Liu, Wenjun (VerfasserIn)
Weitere Verfasser: Sharp, Ian D, Tilley, T Don
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S. Hydrocarbons, Chlorinated Indicators and Reagents Hydrogen 7YNJ3PO35Z dichlorocarbene E73HG1090V Silicon Z4152N8IUI