Growth and stabilization of silver nanoparticles on carbon dots and sensing application

Carbon dots (C-dots) have been proven to show the capability for direct reduction of Ag(+) to elemental silver (Ag(0)) without additional reducing agent or external photoirradiation by incubating Ag(+) with C-dots for 5 min in a water bath at 50 °C. Silver nanoparticles (Ag-NPs) are simultaneously f...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 52 vom: 31. Dez., Seite 16135-40
1. Verfasser: Shen, Liming (VerfasserIn)
Weitere Verfasser: Chen, Meiling, Hu, Linlin, Chen, Xuwei, Wang, Jianhua
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Reducing Agents Silver 3M4G523W1G Carbon 7440-44-0
Beschreibung
Zusammenfassung:Carbon dots (C-dots) have been proven to show the capability for direct reduction of Ag(+) to elemental silver (Ag(0)) without additional reducing agent or external photoirradiation by incubating Ag(+) with C-dots for 5 min in a water bath at 50 °C. Silver nanoparticles (Ag-NPs) are simultaneously formed with an average size of 3.1 ± 1.5 nm and grew on carbon dots. This process involves the oxidation of amine or phenol hydroxyl groups on the aromatic ring of C-dots. Meanwhile C-dots protect and stabilize the Ag-NPs from aggregation in aqueous medium; that is, the Ag-NPs are stable at least for 45 days in aqueous medium. The formed Ag-NPs cause significant resonance light scattering (RLS), which correlates closely with the concentration of silver cation, and this facilitates quantitative detection of silver in aqueous medium
Beschreibung:Date Completed 27.08.2014
Date Revised 31.12.2013
published: Print-Electronic
Citation Status MEDLINE
ISSN:1520-5827
DOI:10.1021/la404270w