25th anniversary article : Design of polymethine dyes for all-optical switching applications: guidance from theoretical and computational studies

© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 26(2014), 1 vom: 08. Jan., Seite 68-83
1. Verfasser: Gieseking, Rebecca L (VerfasserIn)
Weitere Verfasser: Mukhopadhyay, Sukrit, Risko, Chad, Marder, Seth R, Brédas, Jean-Luc
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S. all-optical switching electronic structure theory polymethines/cyanines third-order nonlinear optics
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520 |a All-optical switching--controlling light with light--has the potential to meet the ever-increasing demand for data transmission bandwidth. The development of organic π-conjugated molecular materials with the requisite properties for all-optical switching applications has long proven to be a significant challenge. However, recent advances demonstrate that polymethine dyes have the potential to meet the necessary requirements. In this review, we explore the theoretical underpinnings that guide the design of π-conjugated materials for all-optical switching applications. We underline, from a computational chemistry standpoint, the relationships among chemical structure, electronic structure, and optical properties that make polymethines such promising materials 
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650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
650 4 |a all-optical switching 
650 4 |a electronic structure theory 
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650 4 |a third-order nonlinear optics 
700 1 |a Mukhopadhyay, Sukrit  |e verfasserin  |4 aut 
700 1 |a Risko, Chad  |e verfasserin  |4 aut 
700 1 |a Marder, Seth R  |e verfasserin  |4 aut 
700 1 |a Brédas, Jean-Luc  |e verfasserin  |4 aut 
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