One F-octyl versus two F-butyl chains in surfactant aggregation behavior

An easy synthetic procedure in two or three steps from perfluoroalkylethyl iodide derivatives led to six novel fluorinated carboxylates monomeric and gemini surfactants with one or two hydrophobic tails, respectively: RF(C2H4)CH(CO2(-))2,2Na(+) and [RF(C2H4)]2C(CO2(-)),Na(+), where RF = C4F9, C6F13,...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 48 vom: 03. Dez., Seite 14815-22
1. Verfasser: Dramé, Abdoulaye (VerfasserIn)
Weitere Verfasser: Taffin de Givenchy, Elisabeth, Dieng, Samba Yandé, Amigoni, Sonia, Oumar, Mamadou, Diouf, Alioune, Darmanin, Thierry, Guittard, Frédéric
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a One F-octyl versus two F-butyl chains in surfactant aggregation behavior 
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520 |a An easy synthetic procedure in two or three steps from perfluoroalkylethyl iodide derivatives led to six novel fluorinated carboxylates monomeric and gemini surfactants with one or two hydrophobic tails, respectively: RF(C2H4)CH(CO2(-))2,2Na(+) and [RF(C2H4)]2C(CO2(-)),Na(+), where RF = C4F9, C6F13, and C8F17. These anionic surfactants exhibited very low surface tension from 15 to 33 mN/m as well as low critical micelle concentration until 1.3 × 10(-4) mol/L. Furthermore, the surface properties of the gemini compound with two short fluoroalkyl chains (RF = C4F9) were found to be almost equal to those of the monomeric surfactant with one long fluoroalkyl chain (RF = C8F17), which could provide an interesting alternative to the bioaccumulative long-chain perfluorinated surfactant 
650 4 |a Journal Article 
700 1 |a Taffin de Givenchy, Elisabeth  |e verfasserin  |4 aut 
700 1 |a Dieng, Samba Yandé  |e verfasserin  |4 aut 
700 1 |a Amigoni, Sonia  |e verfasserin  |4 aut 
700 1 |a Oumar, Mamadou  |e verfasserin  |4 aut 
700 1 |a Diouf, Alioune  |e verfasserin  |4 aut 
700 1 |a Darmanin, Thierry  |e verfasserin  |4 aut 
700 1 |a Guittard, Frédéric  |e verfasserin  |4 aut 
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