Influence of the redox indicator reaction on single-nanoparticle collisions at mercury- and bismuth-modified Pt ultramicroelectrodes
Single-Pt nanoparticles (NPs) can be detected electrochemically by measuring the current-time (i-t) response associated with both hydrazine oxidation and proton reduction during individual Pt NP collisions with noncatalytic Hg- and Bi-modified Pt ultramicroelectrodes (Hg/Pt and Bi/Pt UMEs, respectiv...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 48 vom: 03. Dez., Seite 15100-6 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2013
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Single-Pt nanoparticles (NPs) can be detected electrochemically by measuring the current-time (i-t) response associated with both hydrazine oxidation and proton reduction during individual Pt NP collisions with noncatalytic Hg- and Bi-modified Pt ultramicroelectrodes (Hg/Pt and Bi/Pt UMEs, respectively). At Hg/Pt UMEs, the i-t response for both hydrazine oxidation and proton reduction consists of repeated current "spikes" that return to the background level as Hg poisons the Pt NP after collision with the Hg/Pt UME due to amalgamation and deactivation of the redox reaction. Furthermore, at a Hg/Pt UME, the applied potential directly influences the interfacial surface tension (electrocapillarity) that also impacts the observed i-t response for single-Pt NP collisions for proton reduction that exhibits a faster decay of current (0.7-4 ms) to background levels than hydrazine oxidation (2-5 s). Because the surface tension of Hg is lower (-0.9 V), Pt NPs possibly react faster with Hg (amalgamate at a faster rate), resulting in sharp current spikes for proton reduction compared to hydrazine oxidation. In contrast, a stepwise "staircase" i-t response is observed for proton reduction for single-Pt NP collisions at a Bi/Pt UME. This different response suggests that electrostatic forces of negatively charged citrate-capped Pt NPs also influence the i-t response at more negative applied potentials, but the Pt NPs do not poison the electrochemical activity at Bi/Pt UMEs |
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| Beschreibung: | Date Completed 25.09.2014 Date Revised 04.02.2014 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la402818g |