Investigation of adsorption capacity of N-carboxymethyl chitosan for Pb(II) ions

N-carboxymethyl chitosan (NCMC) was prepared by reacting chitosan (CTS) with chloroacetic acid and characterized by (13)C-NMR spectroscopy to confirm that carboxymethylation occurred only in the amino groups. The adsorption properties of CTS, NCMC and O-carboxymethyl chitosan (OCMC) towards Pb(II) i...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 68(2013), 8 vom: 28., Seite 1873-9
1. Verfasser: Wang, Chongxia (VerfasserIn)
Weitere Verfasser: Song, Qingping, Gao, Jiangang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't O-carboxymethylchitosan Water Pollutants, Chemical Lead 2P299V784P N-(carboxymethyl)chitosan 83512-85-0 Chitosan 9012-76-4
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520 |a N-carboxymethyl chitosan (NCMC) was prepared by reacting chitosan (CTS) with chloroacetic acid and characterized by (13)C-NMR spectroscopy to confirm that carboxymethylation occurred only in the amino groups. The adsorption properties of CTS, NCMC and O-carboxymethyl chitosan (OCMC) towards Pb(II) ions were evaluated and the order of the adsorption capacity was as follows: NCMC > OCMC > CTS. The effects of initial pH value (2.0-5.5) of the solutions and contact time (5-120 min) on adsorption of Pb(II) were investigated and the kinetic data were evaluated using the pseudo-first-order and pseudo-second-order models. Kinetics study showed that the adsorption process followed second-order kinetics rather than the first-order one. Furthermore, the experimental equilibrium data of Pb(II) on the NCMC were analyzed using the Langmuir and Freundlich isotherm models and the results indicated that the Langmuir model gave a better fit than the Freundlich equation and the maximum adsorption capacity obtained from the Langmuir model was 421.9 mg g(-1) 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Water Pollutants, Chemical  |2 NLM 
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650 7 |a N-(carboxymethyl)chitosan  |2 NLM 
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650 7 |a Chitosan  |2 NLM 
650 7 |a 9012-76-4  |2 NLM 
700 1 |a Song, Qingping  |e verfasserin  |4 aut 
700 1 |a Gao, Jiangang  |e verfasserin  |4 aut 
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