Synthesis and coordinative layer-by-layer deposition of pyridine-functionalized gold nanoparticles and tetralactam macrocycles on silicon substrates

Coordination chemistry was applied to deposit pyridine-functionalized gold nanoparticles on silicon substrates. The particles were synthesized through the Brust/Schiffrin route with a subsequent ligand exchange reaction yielding well-defined particles of two different sizes. Multilayer deposition wa...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 29(2013), 46 vom: 19. Nov., Seite 14284-92
1. Verfasser: Traulsen, Christoph H-H (VerfasserIn)
Weitere Verfasser: Kunz, Valentin, Heinrich, Thomas, Richter, Sebastian, Holzweber, Markus, Schulz, Andrea, von Krbek, Larissa K S, Scheuschner, Ulf T J, Poppenberg, Johannes, Unger, Wolfgang E S, Schalley, Christoph A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Coordination chemistry was applied to deposit pyridine-functionalized gold nanoparticles on silicon substrates. The particles were synthesized through the Brust/Schiffrin route with a subsequent ligand exchange reaction yielding well-defined particles of two different sizes. Multilayer deposition was carried out on a pyridine-terminated SAM, anchored on a hydroxyl-terminated silicon surface. Analogously, Hunter/Vögtle-type tetralactam macrocycle multilayers were deposited as well as mixed layers containing both either in an alternating sequence or as a macrocycle multilayer with a terminating nanoparticle layer. These composite layers were examined with respect to their ability to bind squaraine axles in the macrocycle cavities. The amount of guest bound is higher for the composite layer with alternating macrocycles and nanoparticles 
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700 1 |a Kunz, Valentin  |e verfasserin  |4 aut 
700 1 |a Heinrich, Thomas  |e verfasserin  |4 aut 
700 1 |a Richter, Sebastian  |e verfasserin  |4 aut 
700 1 |a Holzweber, Markus  |e verfasserin  |4 aut 
700 1 |a Schulz, Andrea  |e verfasserin  |4 aut 
700 1 |a von Krbek, Larissa K S  |e verfasserin  |4 aut 
700 1 |a Scheuschner, Ulf T J  |e verfasserin  |4 aut 
700 1 |a Poppenberg, Johannes  |e verfasserin  |4 aut 
700 1 |a Unger, Wolfgang E S  |e verfasserin  |4 aut 
700 1 |a Schalley, Christoph A  |e verfasserin  |4 aut 
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