|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM231618077 |
| 003 |
DE-627 |
| 005 |
20231224091145.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2013 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la402710r
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0772.xml
|
| 035 |
|
|
|a (DE-627)NLM231618077
|
| 035 |
|
|
|a (NLM)24117251
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Salmi, Zakaria
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Diazonium cation-exchanged clay
|b an efficient, unfrequented route for making clay/polymer nanocomposites
|
| 264 |
|
1 |
|c 2013
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 05.06.2014
|
| 500 |
|
|
|a Date Revised 05.11.2013
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a We describe a simple, off-the-beaten-path strategy for making clay/polymer nanocomposites through tandem diazonium salt interface chemistry and radical photopolymerization. Prior to photopolymerization, sodium montmorillonite (MMT) was ion exchanged with N,N'-dimethylbenzenediazonium cation (DMA) from the tetrafluoroborate salt precursor. DMA acts as a hydrogen donor for benzophenone in solution; this pair of co-initiators permits us to photopolymerize glycidyl methacrylate (GMA) between the lamellae of the diazonium-modified clay, therefore providing intercalated MMT-PGMA nanocomposites with an onset of exfoliation. This work conclusively provides a new approach for bridging reactive and functional polymers to layered nanomaterials via aryl diazonium salts in a simple, fast, efficient cation-exchange approach
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Benzarti, Karim
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chehimi, Mohamed M
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 44 vom: 05. Nov., Seite 13323-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:29
|g year:2013
|g number:44
|g day:05
|g month:11
|g pages:13323-8
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la402710r
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 29
|j 2013
|e 44
|b 05
|c 11
|h 13323-8
|