Edge-selectively sulfurized graphene nanoplatelets as efficient metal-free electrocatalysts for oxygen reduction reaction : the electron spin effect
© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 25(2013), 42 vom: 13. Nov., Seite 6138-45 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2013
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. ball-milling electrocatalysts graphene nanoplatelets oxygen reduction reaction sulfurization Metals Sulfur mehr... |
Zusammenfassung: | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. To replace precious platinum (Pt)-based electrocatalysts for cathodic oxygen reduction reaction (ORR), edge-selectively sulfurized graphene nanoplatelets (SGnP) are synthesized as efficient metal-free electrocatalysts simply by ball-milling pristine graphite in the presence of sulfur (S8 ). The resultant SGnPs exhibit remarkable electrocatalytic activity toward ORR with better tolerance to methanol crossover/CO poisoning effects and longer-term stability than those of pristine graphite and commercial Pt/C electrocatalysts. Edge-Selectively Sulfurized Graphene Nanoplatelets as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction: The Electron Spin Effect |
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Beschreibung: | Date Completed 10.09.2014 Date Revised 30.09.2020 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201302753 |