Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal-Ligand Cooperation
The bis-carbonyl Fe(II) complex trans-[Fe(PNP-iPr)(CO)2Cl]+ reacts with Zn as reducing agent under a dihydrogen atmosphere to give the Fe(II) hydride complex cis-[Fe(PNP-iPr)(CO)2H]+ in 97% isolated yield. A crucial step in this reaction seems to be the reduction of the acidic NH protons of the PNP-...
| Publié dans: | Organometallics. - 1998. - 32(2013), 15 vom: 12. Aug., Seite 4114-4121 |
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| Auteur principal: | |
| Autres auteurs: | , , , , |
| Format: | Article |
| Langue: | English |
| Publié: |
2013
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| Accès à la collection: | Organometallics |
| Sujets: | Journal Article |