Synthesis of raspberry-like poly(styrene-glycidyl methacrylate) particles via a one-step soap-free emulsion polymerization process accompanied by phase separation

We herein report a facile method to prepare raspberry-like poly(styrene-glycidyl methacrylate) [P(S-GMA)] particles with controllable structure via a one-step soap-free emulsion polymerization process accompanied by phase separation. In this method, corona particles with a size of 10-20 nm were prod...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 37 vom: 17. Sept., Seite 11730-41
1. Verfasser: Fan, Xinlong (VerfasserIn)
Weitere Verfasser: Jia, Xiangkun, Zhang, Hepeng, Zhang, Baoliang, Li, Chunmei, Zhang, Qiuyu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Synthesis of raspberry-like poly(styrene-glycidyl methacrylate) particles via a one-step soap-free emulsion polymerization process accompanied by phase separation 
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520 |a We herein report a facile method to prepare raspberry-like poly(styrene-glycidyl methacrylate) [P(S-GMA)] particles with controllable structure via a one-step soap-free emulsion polymerization process accompanied by phase separation. In this method, corona particles with a size of 10-20 nm were produced in situ in the later polymerization stage by the migrating of S-enriched polymers from GMA-enriched core particles. The size of the corona particles and the roughness of the raspberry-like particles can be easily controlled by adjusting the amount of styrene (S), glycidyl methacrylate (GMA), and divinylbenzene (DVB). The structure of raspberry-like P(S-GMA) particles was confirmed by transmission electron microscopy, scanning electron microscopy, and atomic force microscopy. A possible mechanism of the formation of raspberry-like particles was proposed 
650 4 |a Journal Article 
700 1 |a Jia, Xiangkun  |e verfasserin  |4 aut 
700 1 |a Zhang, Hepeng  |e verfasserin  |4 aut 
700 1 |a Zhang, Baoliang  |e verfasserin  |4 aut 
700 1 |a Li, Chunmei  |e verfasserin  |4 aut 
700 1 |a Zhang, Qiuyu  |e verfasserin  |4 aut 
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