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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la402759w
|2 doi
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|a pubmed24n0766.xml
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|a DE-627
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|a eng
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|a Fan, Xinlong
|e verfasserin
|4 aut
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|a Synthesis of raspberry-like poly(styrene-glycidyl methacrylate) particles via a one-step soap-free emulsion polymerization process accompanied by phase separation
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 04.04.2014
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|a Date Revised 17.09.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a We herein report a facile method to prepare raspberry-like poly(styrene-glycidyl methacrylate) [P(S-GMA)] particles with controllable structure via a one-step soap-free emulsion polymerization process accompanied by phase separation. In this method, corona particles with a size of 10-20 nm were produced in situ in the later polymerization stage by the migrating of S-enriched polymers from GMA-enriched core particles. The size of the corona particles and the roughness of the raspberry-like particles can be easily controlled by adjusting the amount of styrene (S), glycidyl methacrylate (GMA), and divinylbenzene (DVB). The structure of raspberry-like P(S-GMA) particles was confirmed by transmission electron microscopy, scanning electron microscopy, and atomic force microscopy. A possible mechanism of the formation of raspberry-like particles was proposed
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|a Journal Article
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|a Jia, Xiangkun
|e verfasserin
|4 aut
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|a Zhang, Hepeng
|e verfasserin
|4 aut
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|a Zhang, Baoliang
|e verfasserin
|4 aut
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|a Li, Chunmei
|e verfasserin
|4 aut
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|a Zhang, Qiuyu
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 37 vom: 17. Sept., Seite 11730-41
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|x 1520-5827
|7 nnns
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|g volume:29
|g year:2013
|g number:37
|g day:17
|g month:09
|g pages:11730-41
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|u http://dx.doi.org/10.1021/la402759w
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