Tunable interactions of polyoxometalate-based brushlike hybrids in solvents of variable quality : from self-recognition to supramolecular recognition

The controllable interactions of a spherical polymer brush modeled by a poly(styrene-b-4-vinylpyridinium methyl iodide)-polyoxometalate composite micelle, SVP-6, with a polyoxometalate-based supramolecular star polymer, PSP-4, in solvents of variable quality allow us to tune their self-assembly beha...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 34 vom: 27. Aug., Seite 10630-4
1. Verfasser: Zhang, Qian (VerfasserIn)
Weitere Verfasser: Liao, Yin, Bu, Weifeng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a The controllable interactions of a spherical polymer brush modeled by a poly(styrene-b-4-vinylpyridinium methyl iodide)-polyoxometalate composite micelle, SVP-6, with a polyoxometalate-based supramolecular star polymer, PSP-4, in solvents of variable quality allow us to tune their self-assembly behaviors from self-recognition to supramolecular recognition. In the former case, isolated, contractive spheres together with a few vesicles formed by PSP-4 coexist with multimicelle aggregates formed by SVP-6, whereas SVP-6 is hosted inside the vesicle of PSP-4 in the latter case. This work represents an important step toward the development and understanding of programmable self-assembly of brushlike polymers into complex materials 
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700 1 |a Bu, Weifeng  |e verfasserin  |4 aut 
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