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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la402622j
|2 doi
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|a eng
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|a Xu, Jun
|e verfasserin
|4 aut
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|a Growth mechanisms of 2D organic assemblies generated from dialkylated melaminium derivatives
|b the length difference of the two alkyl chains that matters
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 13.03.2014
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|a Date Revised 27.08.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a This research is aimed to understand the growth mechanisms for self-assembly of dialkylated melamine derivatives. The dialkylated melamine derivatives with different alkyl chains (Mela-m-n) are able to self-assemble with hydrochloric acid in dichloromethane to form 2D organic assemblies, exhibiting similar lamellar structures as Mela-n·HCl with identical alkyl chains. The most interesting finding is that the growth mechanism of Mela-n·HCl with identical alkyl chains is revealed to be layer growth, while Mela-m-n·HCl with asymmetric alkyl chains adopts a spiral growth mechanism. The asymmetric alkyl chains in Mela-m-n may lead to the formation of dislocation, which is responsible for the spiral growth mechanism
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|a Journal Article
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|a Wu, Guanglu
|e verfasserin
|4 aut
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|a Wang, Zhiqiang
|e verfasserin
|4 aut
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|a Zhang, Xi
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 34 vom: 27. Aug., Seite 10959-63
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:29
|g year:2013
|g number:34
|g day:27
|g month:08
|g pages:10959-63
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|u http://dx.doi.org/10.1021/la402622j
|3 Volltext
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